
(1)已知①C(s)+H2O(g)═CO(g)+H2(g)△H=+131.3kJ⋅mol−1
②CO2(g)+H2(g)═CO(g)+H2O(g)△H=+41.3kJ⋅mol−1
根据盖斯定律,将①−②可得:C(s)+2H2O(g)=CO2(g)+2H2(g)△H=+90kJ⋅mol−1,反应的焓变△H>0,△S>0,根据反应自发进行的判据
△G=△H−T△S<0,所以需要高温下发生,
故答案为:C(s)+2H2O(g)=CO2(g)+2H2(g)△H=+90.0 kJ⋅mol−1;高温。

(1)已知①C(s)+H2O(g)═CO(g)+H2(g)△H=+131.3kJ⋅mol−1
②CO2(g)+H2(g)═CO(g)+H2O(g)△H=+41.3kJ⋅mol−1
根据盖斯定律,将①−②可得:C(s)+2H2O(g)=CO2(g)+2H2(g)△H=+90kJ⋅mol−1,反应的焓变△H>0,△S>0,根据反应自发进行的判据
△G=△H−T△S<0,所以需要高温下发生,
故答案为:C(s)+2H2O(g)=CO2(g)+2H2(g)△H=+90.0 kJ⋅mol−1;高温。